文章标题：SPE131350-From Oil-Prone Source Rock to Gas-Producing Shale Reservoir – Geologic and Petrophysical Characterization of Unconventional Shale-Gas Reservoirs.
作者：Q.R. Passey，K.M. Bohacs，W.L. Esch，R. Klimentidis 以及 S. Sinha（ExxonMobil Upstream Research Co）
摘要：
Many currently producing shale-gas reservoirs are overmature oil-prone source rocks. Through burial and heating these reservoirs
evolve from organic-matter-rich mud deposited in marine, lacustrine, or swamp environments. Key characterization parameters
are: total organic carbon (TOC), maturity level (vitrinite reflectance), mineralogy, thickness, and organic matter type. Hydrogento-
carbon (HI) and oxygen-to-carbon (OI) ratios are used to classify organic matter that ranges from oil-prone algal and
herbaceous to gas-prone woody/coaly material.
Although organic-matter-rich intervals can be hundreds of meters thick, vertical variability in TOC is high (<1-3 meters) and is
controlled by stratigraphic and biotic factors. In general, the fundamental geologic building block of shale-gas reservoirs is the
parasequence, and commonly 10’s to 100’s of parasequences comprise the organic-rich formation whose lateral continuity can be
estimated using techniques and models developed for source rocks.
Typical analysis techniques for shale-gas reservoir rocks include: TOC, X-ray diffraction, adsorbed/canister gas, vitrinite
reflectance, detailed core and thin-section descriptions, porosity, permeability, fluid saturation, and optical and electron
microscopy. These sample-based results are combined with full well-log suites, including high resolution density and resistivity
logs and borehole images, to fully characterize these formations. Porosity, fluid saturation, and permeability derived from core can
be tied to log response; however, several studies have shown that the results obtained from different core analysis laboratories can
vary significantly, reflecting differences in analytical technique, differences in definitions of fundamental rock and fluid properties,
or the millimeter-scale variability common in mudstones that make it problematic to select multiple samples with identical
attributes.
Porosity determination in shale-gas mudstones is complicated by very small pore sizes and, thus, large surface area (and associated
surface water); moreover, smectitic clays that are commonly present in mud have interlayer water, but this clay family tends to be
minimized in high maturity formations due to illitization. Finally, SEM images of ion-beam-milled samples reveal a separate nanoporosity
system contained within the organic matter, possibly comprising >50% of the total porosity, and these pores may be
hydrocarbon wet, at least during most of the thermal maturation process. A full understanding of the relation of porosity and gas
content will result in development of optimized processes for hydrocarbon recovery in shale-gas reservoirs.
